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Triruthenium Dodecacarbonyl

Chemical Formula: Ru3(CO)12
CAS: 15243-33-1

Triruthenium dodecacarbonyl (Ru3(CO)12) is an orange powder with a typical Ru3 core coordination structure, and is an important precursor in organometallic chemistry, coordination chemistry, and catalysis research. Due to its excellent CO ligand exchange properties and cluster structure stability, Ru3(CO)12 has been widely used in the preparation of catalytic materials and high-end research applications.
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Triruthenium Dodecacarbonyl Basic Properties

  • Molecular Formula: C12O12Ru3

  • Appearance: Orange powder

  • Molecular Weight: 639.33

  • Melting Point: 150 °C

  • Solubility: Slightly soluble in hydrocarbons (such as hexane, cyclohexane, benzene) and acetone

  • Storage Conditions: Inert atmosphere, room temperature

  • Package Information: 1kg; 25kg or customized

Triruthenium Dodecacarbonyl Key Features

Unique metal cluster structure

Triruthenium dodecacarbonyl, with its Ru3 core and 12 CO coordinating groups, is a classic example for studying metal-metal bonds and carbonyl coordination systems.

Good stability

This compound is stable at room temperature and pressure, and is easier to store and handle compared to some other metal carbonyl compounds.

Excellent precursor function

Ru3(CO)12 can be used as a starting agent for the synthesis of other ruthenium complexes or materials, especially as a carbon-based cluster source in catalysis and materials preparation.

Highly efficient catalytic performance

As an important member of the carbonyl ruthenium family, it exhibits excellent catalytic activity in a variety of organic transformation reactions. Its catalytic effect stems from the unique interaction between the ruthenium atom cluster and the reactants.

Triruthenium Dodecacarbonyl Main Applications

Catalysis in organic synthesis

Ru3(CO)12 is a key catalyst precursor for metal-catalyzed conversion reactions such as hydrogenation and hydrosilylation. It is used to synthesize various organic compounds, including pharmaceuticals and specialty chemicals.

Hydrogenation and hydrosilylation

This compound is widely used in hydrogenation reactions to reduce alkenes, alkynes, and carbonyl compounds, playing a crucial role in the synthesis of fine chemicals. Furthermore, it is used in hydrosilylation reactions to form silicon-carbon bonds in the production of organosilicon compounds.

Production of ruthenium catalysts

Triruthenium dodecacarbonyl is a precursor for the synthesis of various ruthenium-based catalysts, which are used in catalytic processes across multiple industries, including petrochemicals, pharmaceuticals, and fine chemicals production.

Materials science

It is used to prepare advanced ruthenium-based materials and thin films, contributing to innovations in nanotechnology, electronics, and energy storage devices.

Precautions

  1. This product is sensitive to moisture and prolonged exposure to air. It should be stored in a dry environment under inert gas protection (such as nitrogen) and should be kept away from sunlight and high temperatures.

  2. Avoid storing with oxidants or strong acids to prevent dangerous reactions or decomposition.

  3. Because CO may be released, operations should be carried out in a fume hood to prevent carbon monoxide buildup.

  4. Take personal protective measures during operation to avoid inhaling dust and coming into contact with vapors. If the substance accidentally comes into contact with eyes or skin, rinse immediately with plenty of water and seek medical attention.

  5. Residues or waste liquids containing ruthenium and carbonyl ligands shall be disposed of in accordance with the regulations for the treatment of hazardous chemicals and shall not be discharged into the environment at will.

FAQ

1. Is triruthenium dodecacarbonyl easily decomposed?

It is relatively stable at room temperature and under suitable conditions, but ligand exchange or cluster structure changes may occur under high temperature, light, or the influence of gases (such as H₂, CO).


2. What are the main uses of Ru3(CO)12?

It is mainly used as a catalyst or catalyst precursor in various reactions in organic synthesis, such as [3+2+1] carbonyl cycloaddition, hydrogen transfer catalysis, reductive carbonylation of aromatic nitro compounds, and allyl amination of olefins.


For more information or to purchase Triruthenium Dodecacarbonyl(Ru3(CO)12), please feel free to contact us via jomin@wolfabio.com or WhatsApp(+86 18359103607).

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