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Manganese Pentacarbonyl Bromide

Mn(CO)5Br

CAS: 14516-54-2
 
Manganese pentacarbonyl bromide (Mn(CO)₅Br) is an orange, air- and light-sensitive organometallic compound containing a manganese(I) center coordinated to five carbonyl ligands and one bromide ion. It is a key intermediate in organomanganese chemistry and a versatile precursor for Mn-based catalysts, widely used in homogeneous catalysis, fine chemical synthesis, and materials science.
 
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Product Description

Name: Manganesepenta Carbonyl Bromide
MF: C5HBrMnO5
MW: 275.9
CAS: 14516-54-2
Appearance: Yellow to orange Crystal
Storage conditions: 2-8°C

Key Applications

  • Organomanganese Precursor

Starting material for synthesizing manganese(0) and manganese(I) complexes via ligand substitution or redox reactions.

  • Homogeneous Catalysis

Active in hydroformylation, olefin functionalization, and carbonylation reactions, enabling selective C–C and C–O bond formation.

  • Fine Chemical & Pharmaceutical Synthesis

Facilitates carbonyl insertion, alkylation, and acylation for high-value intermediates.

  • Materials Science

Potential manganese source in CVD/MOCVD processes or advanced functional materials.

  • Academic Research

Model compound for studying metal–ligand bonding, oxidative addition, and organometallic reaction mechanisms.


Custom packaging for R&D or production scale.


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