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Chromium Hexacarbonyl

Chemical Formula: Cr(CO)6
CAS: 13007-92-6

Chromium hexacarbonyl, also known as Cr(CO)6, is a white crystalline solid with excellent thermal stability and high reactivity. It is widely used in organic synthesis, surface coating, and materials research, particularly in aromatic coordination, metallization reactions, and thin film deposition processes.
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Chromium Hexacarbonyl Basic Properties

  • Molecular Formula: 6CO.Cr

  • Appearance: White crystal

  • Molecular Weight: 220.06

  • Melting Point: >150 °C (dec.) (lit.)

  • Boiling Point: 220 °C

  • Density: 1.77 g/mL at 25 °C (lit.)

  • Vapour Pressure: 1 mm Hg ( 36 °C)

  • Solubility: Insoluble in water and ethanol; soluble in ether and chloroform

  • Storage Conditions: Store below +30°C

  • Package Information: 50g, 1kg, 25kg or customized

Chromium Hexacarbonyl Key Features

High purity

The purity of this compound can reach over 99%, meeting the stringent purity requirements for materials in scientific research experiments and semiconductor processes.

Excellent thermal stability

Chromium hexacarbonyl is stable at room temperature, but it can release carbon monoxide under controlled heating to achieve a controlled reaction, making it highly reliable in high-temperature processes such as material deposition.

High controllability of thin film deposition

Cr(CO)6 can provide a uniform metal layer in CVD coating processes and can be used to prepare chromium thin films and special surface materials.

Multifunctionality

It can be used not only for catalysis, but also as a precursor for the synthesis of other chromium-based materials, expanding its applications in nanotechnology and electronics.

Chromium Hexacarbonyl Main Applications

Organic synthesis

In pharmaceuticals and fine chemicals, chromium hexacarbonyl is commonly used as a catalyst to promote the hydrogenation and carbonylation of olefins, for example, to improve efficiency and selectivity in the synthesis of vitamins or fragrances.

CVD thin film deposition

Cr(CO)6 is used in the manufacture of chromium plating and special surface materials, such as optical mirror materials and corrosion-protective coatings.

Materials science and coatings

This compound can be used to prepare high-purity chromium thin films and nanomaterials, forming protective or conductive layers in electronic devices such as semiconductors and solar cells via chemical vapor deposition (CVD).

Industrial catalysis processes

In the petrochemical industry, it participates in polymerization reactions and fuel additive synthesis, helping to optimize production processes and improve product performance while reducing waste.

Precautions

  1. Chromium hexacarbonyl is photosensitive and heat-sensitive, and should be kept away from direct sunlight and heat sources to prevent decomposition. It should also be kept away from moisture and oxidizers, and is best stored under an inert gas atmosphere.

  2. Protective gloves, goggles, and respirators must be worn during operation, and the operation must be carried out in a fume hood.

  3. Avoid direct skin contact or inhalation of vapors. If skin contact occurs, rinse immediately with plenty of water. If inhaled, move to a well-ventilated area and seek medical attention.

FAQ

1. What are the main industrial applications of chromium hexacarbonyl?

It is primarily used as a highly efficient catalyst in organic synthesis and materials preparation, such as accelerating hydrogenation reactions in pharmaceuticals, or depositing chromium coatings in the electronics industry. This reduces energy consumption and improves product purity, meeting industrial demands for efficiency and environmental protection.


2. What is the shelf life of this compound? Under what conditions will it degrade?


Under ideal storage conditions (sealed, dry, and protected from light), chromium hexacarbonyl can be stored for 1-2 years without significant degradation. However, when exposed to moisture, air, or light, it will gradually decompose, producing carbon monoxide and chromium oxides. Therefore, it is crucial to regularly check the storage environment.


For more information or to purchase Chromium Hexacarbonyl(Cr(CO)6), please feel free to contact us via jomin@wolfabio.com or WhatsApp(+86 18359103607).

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