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Cobalt Carbonyl

Chemical Formula: Co2(CO)8
CAS: 10210-68-1

Cobalt Carbonyl, or Co2(CO)8, is an orange-red crystalline solid and an important inorganic metal complex. It plays a crucial role in homogeneous catalysis, fine chemicals, and organic synthesis, particularly exhibiting excellent catalytic activity and selectivity in hydroformylation and carbonylation reactions.
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Cobalt Carbonyl Basic Properties

  • Molecular Formula: C8Co2O8+4

  • Appearance: Orange-red crystal

  • Molecular Weight: 341.95

  • Melting Point: 51-52 °C

  • Boiling Point: 52°C

  • Density: 1.81

  • Vapour Pressure: 9.333-200Pa at 15-25℃

  • Flash Point: -13 °C

  • Solubility: Soluble in alcohol, ether and carbon disulfideSoluble in ether, naphtha and carbon disulfide

  • Storage Conditions: 2-8°C

  • Package Information: 10g;100g;1kg or customized

Cobalt Carbonyl Key Features

High catalytic efficiency

Thanks to the unique metal carbonyl structure of cobalt carbonyl, it provides high conversion and selectivity in hydroformylation, carbonylation, and hydrogenation reactions, exhibiting excellent catalytic efficiency.

Unique structural characteristics

The Co2(CO)8 molecule contains cobalt-cobalt metallic bonds and bridged carbonyl structures. In addition, it exhibits isomer equilibrium in solution. This dynamic structural characteristic is closely related to its catalytic activity.

Mild reaction conditions

It can exert its catalytic effect under medium and low temperature conditions, reducing energy consumption and equipment pressure, and is friendly to reagent-sensitive systems.

Synthetic precursor

This compound is a key starting material for the synthesis of other cobalt complexes (such as tetracarbonylcobaltate anion [Co(CO)4]⁻) and the preparation of high-purity cobalt powder and nano-scale carbonyl cobalt powder.

Cobalt Carbonyl Main Applications

Chemical catalysis

Cobalt carbonyl is the core catalyst for hydroformylation reactions, used in the large-scale production of basic chemical raw materials such as aldehydes and alcohols. It can also catalyze various organic transformations such as alkyne reactions and aromatic hydrocarbon reduction.

Organic synthesis research

This compound participates in the construction of C-C and C-O bonds and can be used to prepare complex intermediates and high-value-added molecules.

New materials and energy

Nanoscale cobalt carbonyl powder, derived from cobalt carbonyl, has wide applications in energy storage (such as battery materials), the electronics industry (such as conductive pastes), and metal processing.

Metal refining and surface treatment

This compound can be used to refine high-purity cobalt metal. It is also used as a coating for metal surfaces to provide protection or specific functions, such as in CVD applications.

Precautions

  1. Cobalt carbonyl should be sealed, protected from light, and stored in a dry environment at low temperature (2-8℃) to avoid decomposition and oxidation caused by air and moisture. It is recommended to store it in an inert atmosphere.

  2. This product is highly flammable, with a flash point of only -13 °C. It must be kept away from open flames, heat sources, and oxidizers. Smoking and open flames are strictly prohibited in the work area, and explosion-proof facilities must be provided.

  3. Protective glasses, gloves, and respirators should be worn during the operation to avoid direct skin contact.

  4. If contact with skin, wash with plenty of water and soap. If contact with eyes, rinse immediately with water for at least 15 minutes and seek medical attention.

  5. Waste should be treated as cobalt-containing hazardous chemicals and is strictly prohibited from being discharged into the environment or ordinary waste systems.

FAQ

1. What special precautions should be taken when using and storing Co2(CO)8?

The most critical factors are its flammability and sensitivity to air. It must be stored in a sealed container under low temperature and inert gas protection, and strictly away from sources of ignition and oxidizers.


2. What reactions is cobalt carbonyl primarily used in?

It is mainly used in catalytic systems such as hydroformylation, carbonylation, organic reduction, and C–C bond construction.


For more information or to purchase Cobalt Carbonyl(Co2(CO)8), please feel free to contact us via jomin@wolfabio.com or WhatsApp(+86 18359103607).

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